To better detail Ratchet and Clank, try to collect them in order. R&C, Going Commando, Up Your Arsenal. Deadlocked is the fourth and by far the easiest to find, but it was not all that good. They took a great platforming game and kind of made it into a strict arena fighter with less weapons to play with. Two new R&C games were ported from the PSP to the PS2: Size Matters and Secret Agent Clank. Both are okay. Size Matters is actually better on the PS2 than its hand-held counterpart.
Way of the Samurai is a good game. I enjoyed the first far more than the second, simply because you could pretty much do whatever you wanted in the first. In the second you were given too many places to go and were expected to get jobs.
Guilty Gear X was a nice fighter, though the sequels gave my thumb blisters.
And if you want to collect some RPGs (though there are many better rpgs for the PS1), look out for the first game in the .Hack series (which I forgot the name of), Arc the Lad: Twilight of the Spirits/3, Star Ocean: Til the End of Time, the two WildArms PS2 games (3 and a remake of 1), the two DarkCloud games, Tales of the Abyss, FF12, and Grandia 2.