zumbledum said:
I think you're thinking about this a bit too hard. But hey!
Consider how energy from the sun impacts earth. Currently, light that comes in is largely refracted in the atmosphere, or bounced back into space from the cloud layer.
If it GETS to the surface of the earth, right now, you've got part of it hitting asphalt roads, some of which bounces off back into the atmosphere. Some of it, however, is absorbed due to the asphalt being a dark color, and is retained as heat.
However, this heat is non-permanent, and is bled off back into either the ground or the air over the course of the day as it gets cooler.
Percentages-wise, I don't imagine it's likely to impact things on a large scale.
As they're using glass, you're still getting some reflecting back off of it into the atmosphere(actually likely a much higher percentage than the asphalt), and some of it is being absorbed into the solar cells for energy instead of heat, as in the case with asphalt.
From there, the cells could either heat the cells, making it act identically to asphalt, or whisk it away to be used elsewhere as electricity. So at most, you'd get a very minute variation in ground-level temperatures during the daylight hours where roads are. Given that the glass surface is likely to reflect back a comparatively larger percentage of light and energy than the dark asphalt, it would likely even-out the amount of energy going into the atmosphere at ground-level.
So the likelyhood of it being an appreciable enough difference to have huge impacts on the weather or environment is pretty astoundingly unlikely.
Obviously to be sure you'd need to run some kind of simulation to see if there's any real impact, but but a rough thought-experiment and my gut says it wouldn't.