Brimstone & Almost Human.
Brimstone was a 90s cop procedural about a corrupt cop who gets killed, goes to hell, then makes a deal with the devil after 100&something of the worst souls in history escape satan's clutches. Wasn't an awesome show, but it was entertaining. Got canned after a season.
Almost Human was, well, it was kinda Deus Ex meets I, Robot in a tv show. It was only on air for about 10 episodes, sadly, and a couple of the episodes were aired out of order. Hell, it had Karl Urban as the primary lead. Unsurprisingly, Fox canned it like they do every show that's half-way niche.