For me James Tiberius Kirk is the best captain between the two. Both are very good but Kirk did things that were illegal to the Federation. He knew it was, but he still went with it. He also went back in time in Star Trek IV The Voyage Home.
Now Jean Luc Picard was also great, he made decisions that could become fatal. He fought along side Kirk in Star Trek Generations. He also went into the Nexis and made it back safely.
Now Jean Luc Picard was also great, he made decisions that could become fatal. He fought along side Kirk in Star Trek Generations. He also went into the Nexis and made it back safely.