Okay, it depends.
What superpower I had.
How easily I could get paid for my good duties.
If I had a superpower like, curing any illness, then I'd demand cash from the UN and go over to wherever they send me.
However, if it was the ability to make something explode simply by wanting it exploded.
Then, my morals might be a bit lax, but I'd be on the goodies side... Probably...
Alternatively, I very well might just chill out at a bar, and do some vigilante justice (which I voted for) and steal a living from the drug dealers I hunt.
Transituational thinking, it's impossible.