Quistis from FF8, is one for me, mostly because I can relate to her character. (Er, not the overachieving prodigy part XD

Frustrated easily by personal problems, unable to connect with the person you like, and constantly questioning yourself despite putting out a stronger image. (Quistis vs Franziska whip battle, anyone?)
Hmm .. Garnet from FF9, I'll also add. I was wondering if anyone would be nifty like Tifa in FF7, having been forced to deal with Rinoa in FF8, and Garnet was a refreshing character. She was a princess and sheltered, but she took matters into her own hands, and was steadfast in that. She went through a hell of a lot, but still came out of it a better person. Plus, she put Zidane in his place. XD I was rather fond of her, really.
I'll join in the PW female character debate! I'll pick Ema Skye. XD I know, she was supposed to be a Maya clone to be Phoenix's sidekick in the fifth case of the first game, since Maya was back in Kurain, but in Apollo Justice, she really grew up and .. well, became insanely touchy. I don't know why, I liked the fact that they had her fail her proficiency exam and have to be a detective. She's following her sister's path (probably one of the reasons she's so irritable about it) and she's got some pretty nifty one-liners in the game ("Why can't we have a straight-forward killing in this country?!") And .. yeah. She's my pick. <3
/ramble