Azrael From Gundam SEED,the governer from walking dead,the illusive man,Joffrey Lannister,Cersei Lannister,Ramsey Bolton and,although not a direct villain,Daenerys Targarynen.
What I like about the Song Of Ice and fire series is that you can paint villains as anti heroes,well,except Joffrey,the snobby litle **** along with his powermad ***** of a mother.
Now,where was I? yes, you can pai t heroes as villains.Daenerys,Instead of Marching on Westeros just when here strength of her army was full,and when chaos in Westeros was high decided to try and bring order to a city with diseases,religous cults,crime and other nasty thing.
Ramsey Just sickens me,but I do like what does to Theon,hated the bastard from the minute he was introduced.
Illusive man is like a republican politician.He tries to do good,but ends up using everything to spread his agenda and power.Killing him in ME3 was really underplayed and not satisfying.
George RR martin does a great job of portraying characters and making us hate them without blatant exposition.He sets up their personalities to be hated,not just saying OMG HE KILLS PUPPIES AND KILLS KIDS AND STUFF HATE HIM HATE HIM AAAAAAAAAAAAAA.
Kai Friggin leng deserves mention.He seemed so arrogant,acting like theperfect killer,but seeing him lose against thane in hand to hand combat before he killed him cheaply made me think of him as acting like the perfect assasin,but being the brutal and skill less soldier he really was.
Seeing the bastard drown in his own blood after countless sniper shots was satisfying.